Five-Man Band/Anime E-H

Et Cetera

The Hero	Mingchao
The Lancer	Baskerville
The Big Guy	Benkate
The Smart Guy	Fino
The Chick	Yaghi
The Sixth Ranger	Alternate (Also doubles as another The Smart Guy.)

Eyeshield 21

The Hero	Sena
The Lancer	Monta
The Big Guy	Kurita
The Smart Guy	Hiruma
The Chick	Mamori (Team Mom), later Suzuna (standard)

Excel Saga (manga)

The Hero	Matsuya
The Lancer	Watanabe
The Smart Guy	Sumiyoshi
The Big Guy	Ropponmatsu I or II (depending on which one is working)
The Chick	Iwata

Excel Saga (anime)

The Hero	Iwata
The Lancer	Matsuya
The Big Guy	Roponmatsu 1
The Smart Guy	Sumiyoshi
The Chick	Watanabe
Tagalong Kid	Ropponmatsu 2

• Keep in mind that when they form into an actual team, its as a parody of Sentai heroes, so it's hard to figure out who actually fits the role and who is a parody of that role.

Fairy Tail

The Hero	Natsu Dragneel
The Lancer	Gray Fullbuster
The Smart Guy	Happy
The Big Guy	Erza Scarlet
The Chick	Lucy Heartfilia
Sixth Ranger	Elfman Strauss or Gajeel Redfox
Tagalong Kid	Wendy Marvel

The B Team from the latest Tournament Arc might just fit this trope better than the protagonists.

The Hero	Gajeel Redfox
The Lancer	Juvia Loxar
The Smart Guy	Jellal Fernandes, disguised as Mystogan.
The Big Guy	Laxus Dreyar
The Chick	Mirajane Strauss
Sixth Ranger	Cana Alberona

Fang Of The Sun Dougram

The Hero	Rocky
The Lancer	Festa, later Crinn
The Smart Guy	Crinn, later Henkel
The Big Guy	Chico and/or Nanashi
The Chick	Canary, later Rita
Kid Appeal Character	Billy
Tagalong Kid	George
Team Pet	Nanashi

Flame of Recca: Team Hokage

The Hero	Recca Hanabishi
The Lancer	Tokiya Mikigami
The Smart Guy	Kaoru Koganei
The Big Guy	Domon Ishijima
The Chick (Action Girl)	Fuuko Kirisawa
The Chick (The Medic)	Yanagi Sakoshita
Team Mom	Kagehoshi

Fullmetal Alchemist - The Military

The Hero	Roy Mustang
The Lancer	Lt. Riza Hawkeye (She's always by Mustang's side, serving as his sole confidante - she is also the highest ranked besides Mustang, and generally level-headed where the other guys are completely lost. She also keeps Mustang on track and serves as his bodyguard on occasion. Considering the implied relationship, she's almost a cross between being his Battle Butler and his Violently Protective Girlfriend.)
The Big Guy	Lt. Jean Havoc (It seems Breda would be, but Havoc is the most experienced (aside from Hawkeye and Mustang) in combat. Serves more in this capacity in the manga then the anime, in the anime he serves as more of the team butt monkey or even the Chick then anything else.)
The Smart Guy	Lt Heymans Breda, WO Vato Falman (He looks like the big guy, but truth is Breda is a tactical genius, though this is more an informed ability then anything else. He often does the espionage work for Mustang, including picking up Dr Marcoh, supervising illegal border crossings, and interrogating Maria Ross. Warrant Officer Falman might also count considering he has a photographic memory and a more 'Spock' like manner.)
Tagalong Kid	Master Sergeant Kain Fuery (He's the techie, almost useless at fighting, and has the lowest rank of all the assembled team. He'd be the smart guy, except Breda and Falman are much smarter then he is. Often gets in the way when fighting breaks out.)
The Mentor	Lt. Gen. Grumman (Specifically, Mustang's mentor in the manga.)
Team Pet	Black Hayate

Scar's group

The Anti-Hero	Scar
The Lancer	Mei Chang
The Smart Guy	Dr. Marcoh
The Big Guys	Jerso and Zampano (also count as Those Two Guys)
The Chick	Yoki
Team Pet	Xiao May

Ed's later group

The Hero	Ed
The Lancer(s)	Greedling
The Smart Guy	Hohenheim (once he joins; before that Ed or Ling- Ed's smarter but Ling is the best battle strategist)
The Big Guys	Darius and Heinkel (also count as Those Two Guys)
Action Girl	Lan Fan
The Mentor	Fuu

Fushigi Yuugi: Suzaku warriors

Big Good	Miaka
The Hero	Tamahome
The Lancer	Tasuki
The Big Guy	Nuriko (slight subversion, he's a Cute Bruiser more than a standard Big Guy)
The Smart Guy	Chichiri
The Chick	Hotohori (Royalty, So Beautiful It's a Curse, fights like a Lady of War, sits out battle during the second half of the series.)
The Medic	Mitsukake
Tagalong Kid	Chiriko

Future GPX Cyber Formula: Sugo Asurada

The Hero	Hayato Kazami
The Lancer	Miki Jounouchi (also the Cool Big Sis)
The Smart Guy	Shinsuke Maki
The Chick	Asuka Sugo
Tagalong Kid	Ryohei Sumi (although he's not the youngest of the team)
The Mentor	Tetsuichiro Kurumada (also Team Dad)
Team Pet	V-8
Sixth Ranger	Knight Schumacher/Osamu Sugo

Gash Bell (After the Zophise arc)

The Hero	Gash
The Lancer	Umagon
The Big Guy	Wonlei
The Smart Guy	Kanchome
The Chick	Tio
The Sixth Ranger	Brago

Gakkou no Kaidan

The Hero	Satsuki Miyanoshita
The Lancer	Hajime Aoyama
The Smart Guy	Reo Kakinoki (odd case: he's got lots of booksmarts and technical knowledge, but is the one with MORE What an Idiot! moments due to his lack of common sense)
The Big Guy and The Chick	Momoko Koigakubo (she's a sweet Ill Girl and a Distressed Damsel, but is also the tallest and oldest of the group and has channelized powerful spirits specifically, Satsuki's mother's ghost at least twice)
Tagalong Kid	Keiichirou Miyanoshita
The Mentor	Amanojyaku (also Team Pet) and Kayako
Sixth Ranger	Kayako, from beyond the grave. Usually by possessing Momoko's body.

GetBackers has a revolving cast of Loads and Loads of Characters. The main characters, Ban and Ginji, tend to stay the same, but who fills the other roles depends on who was tapped for whatever mission there is and what elements of their past are currently making hell for everyone. Divine Design arc

The Hero	Ginji
The Lancer	Ban
The Smart Guy	Himiko
The Chick(s)	Hevn, Kazuki (Captured & brainwashed early on)
The Mentor	Maria
Sixth Ranger / The Big Guy	Juubei

GetBackers - Kazuki's old gang, Fuuga (lit. "Elegance")

The Hero	Kazuki
The Lancer	Juubei
The Big Guy	Toshiki
The Smart Guy	Saizou
The Chick (Team Mom)	Sakura

GetBackers - IL Recovery Team

The Hero	Ginji
The Lancer	Ban
The Big Guy	Shido
The Smart Guy	Kazuki
The Chick(s)	Himiko, Hevn
Sixth Ranger	Akabane

GetBackers - The Shiki (lit. "Seasons") Clan

The Hero	Shido Fuyuki
The Lancer	Amon Natsuki
The Big Guy	Ryuho Agi
The Chick (The Medic)	Kaoru Haruki

GetBackers - Stradivarius Recovery Team

The Hero	Ginji
The Lancer	Ban
The Big Guy	Hevn
The Smart Guy	Madoka
The Chick(s)	Natsumi, Paul
Sixth Ranger	Shido

GetBackers - Venus de Milo arc

The Hero	Ginji
The Lancer	Ban
The Big Guy	Shido
The Chick	Emishi

GetBackers - VOLTS gang leaders

The Hero	Ginji (Lightning Emperor)
The Lancer	Masaki (Ruler of Light, Flash Master)
The Big Guy	Shido (Beastmaster)
The Smart Guy	Makubex (The Unknown Boy, Electric Brain)
The Chick The (other) Smart Guy	Kazuki (Kazuki of the Strings, Prince of Fear)

• Collectively, Kazuki, Shido, Makubex and Masaki are known as the Four Kings.

Getter Robo (Original and G)

The Hero	Ryoma Nagare
The Lancer	Hayato Jin
The Smart Guy and The Chick	Michiru Saotome
The Big Guy	Musashi Tomoe, later Benkei Kurama
Tagalong Kid	Genki Saotome
The Mentor	Dr. Saotome

Ginga Densetsu Weed (More of an entire pack, but still)

The Hero	Weed
The Lancer(s)	Jerome, Kyoushiro and GB
The Big Guy	Hiro
The Smart Guy(s)	Rocket and Tesshin
The Chick	Reika
Sixth Ranger(s)	Hook and Sasuke
Tagalong Kid	Mel

Ginga: Nagareboshi Gin

The Hero	Gin
The Lancer(s)	John and Ben
The Big Guy	Moss
The Smart Guy	Smith
The Chick	Cross
Sixth Ranger(s)	Wilson and Hakuro

GoLion

The Hero	Akira Kogane
The Lancer	Isamu Kurogane
The Big Guy	Tsuyoshi Seido
The Smart Guy	Hiroshi (Chibi) Suzuishi
The Chick	Princess Fala
Sacrificial Lamb	Takashi Shirogane
Sixth Ranger	Ryou Shirogane (Takashi's Backup Twin)

Gravion

The Hero	Touga (subverted: he's not the main character)
The Lancer	Eiji (... he is)
The Smart Guy	Eina
The Big Guy	Mizuki (*ahem*)
The Chick (subverted)	Luna
Sixth Ranger	Leele

Gunslinger Girl

The Hero	Henrietta
The Lancer	Rico
The Smart Guy	Claes (Initially), Angelica
The Big Guy	Triela
The Chick	Claes (After her handler Raballo died, she could not participate in missions)

Gunslinger Girl -Il Teatrino-

The Hero	Triela
The Lancer	Henrietta
The Smart Guy	Angelica
The Big Guy	Rico
The Chick	Claes

Gunsmith Cats

The Hero	Rally
The Lancer	Misty
The Smart Guy	Becky
The Big Guy	Bean
The Chick	May

Hamtaro

The Hero	Hamtaro
The Lancer(s)	Oxnard and Boss
The Big Guy(s)	Howdy, Snoozer, and Stan
The Smart Guy(s)	Dexter, Panda, and Maxwell
The Chick(s)	Bijou, Pashmina, and Sandy
Tagalong Kid(s)	Cappy and Penelope
The Mentor(s)	Elder Ham and Auntie Viv
Sixth Ranger(s)	Jingle, Sabu, and Pepper

Heartcatch Pretty Cure

The Hero	Tsubomi/Cure Blossom
The Lancer	Erika/Cure Marine
The Big Guy/The Chick	Itsuki/Cure Sunshine
The Smart Guy	Yuri/Cure Moonlight
The Mentor	Kaoruko
Team Pet	Chypre, Coffret, Potpourri

High School DxD: Occult Research Club

The Hero	Issei Hyodo
The Lancer	Yuuto Kiba
The Big Girls	Akeno Himejima, Koneko Toujou, and Xenovia
The Smart Girl and The Leader	Rias Gremory
The Chick (The Medic version)	Asia Argento
The Chick (Tagalong Kid version)	Gasper Vladi
The Mentor	Azazel
Sixth Rangers	Irina Shido, Rossweiss, and Ravel Phenex

High School DxD: Chaos Brigade Vali's Group

The Hero	Vali Lucifer
The Lancer	Bikou
The Big Girl	Kuroka
The Smart Guy	Arthur Pendragon
The Chick	Le Fay Pendragon
Team Pet	Fenrir and Gogmagog

Highschool of the Dead

The Hero	Takashi
The Lancer	Rei
The Big Guy (Genius Bruiser)	Saeko
The Smart Guy	Saya, Hirano (sometimes The Chick, sometimes The Mentor)
The Chick (The Medic version)	Shizuka
The Chick (Tagalong Kid version)	Alice
Team Pet	Zeke

Historys Strongest Disciple Kenichi - The Masters of Ryozanpaku

The Hero	Akisame
The Lancer	Sakaki
The Big Guy	Apacahi
The Smart Guy	Ma Kensei
The Chick	Shigure
Sixth Ranger	The One-Man Army known as "The Elder"

And the members of Shinpaku Alliance:

The Hero	Kenichii
The Lancer	Takeda
The Big Guy	Ukita
The Smart Guy	Nijima
The Chick	Miu
Sixth Ranger	All the former fists

Hunter X Hunter

The Hero	Gon
The Lancer	Killua
The Big Guy	Leorio (Although he also functions as The Medic)
The Smart Guy	Kurapika
The Mentor	Wing, and later Biscuit