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Totooria Helmold (Totori)
Protagonist of the game. She is Rorona's first and only student in alchemy. She's weak and not very smart but alchemy has given her more confidence in herself. Decides to become an adventurer in order to find her mother.
- Childhood Friends: with Gino
- Curtains Match the Window
- Giant Waist Ribbon
- Girly Run
- Gray Eyes
- Nice Girl
- Nice Hat: As with all Atelier Series heroines.
Totori's childhood friend. He wishes to become the world's greatest adventurer and drags Totori along with him. Tends to be hyper and very loud.
- Always Save the Girl: Feels this way regarding Totori.
- Childhood Friends: with Totori
- Cross-Dressing Voices: In the Japanese dub.
- Expy: Hair of Gold? Green Eyes? Keet? Not afraid to speak his mind? Good-looking? He's basically an older Oz.
- Green Eyes
- Hair of Gold
- Heroes Prefer Swords
- Innocently Insensitive: All the time. He doesn't seem to have any concept that people don't like being called old or weak or other derogatory terms (unless he does).
Ceci's childhood friend and adventurer mentor to Totori. Despite her looks, she is abnormally strong and powerful
- Action Girl
- An Axe to Grind
- Bare-Fisted Monk: Though her special attack has her throwing her axe away to wail on her enemies barehanded.
- Boobs of Steel: In brute physical strength only, she is possibly the strongest person in the country. She's also the bustiest.
- Skinship Grope: Does this to virtually every female she meets.
- Tomboy and Girly Girl: Tomboy to Ceci's girly girl.
Mimi Houllier von Schwarzlang
An aristocrat who wishes to become a famous adventurer to bring pride to her family name. She's prideful, snooty, and tends to be quite selfish, but she has a good heart.
- Action Girl
- Foil: To Cordelia. Both of them are Tsundere aristocrats, yet while Mimi views the title as something important that warrants immediate respect, Cordelia thinks nothing much of it.
- Jerk with a Heart of Gold
- Lady of War: She obviously wants to be one and has the aesthetic down in combat. She's still a bit too immature to really pull it off, though.
- Tsundere: While she is a natural tsundere, it tends to be even worse when it comes to Totori.
A scientist living in Arland.
- Friend to All Children: To the point where he's sadden that not all children seem to be fond of him and his robots.
- Mad Scientist: While not particularly dangerous, he certainly fits the 'mad' part.
- Rocket Punch: His main attack
Cecilia Helmold (Ceci)
Totori's elder sister. Since their mother disappeared, she's taken charge of the household. She was initially opposed to Totori becoming an adventurer, but she eventually relented, though she still doesn't approve much.
- Hair Decorations
- Improbable Weapon User: In her DLC, she uses a feather duster as her Weapon of Choice.
- Promotion to Parent: Even though their father is still alive, Ceci is pretty much like a mother to Totori. It doesn't help that their father is mostly useless.
- Tomboy and Girly Girl: Girly girl to Melvia's tomboy.
Totori and Ceci's father. He tends to be very quiet and calm, to the point people tend to not notice him when he's in a room. Spends most of his time fishing.
A famous adventurer and mother of Ceci and Totori. She disappeared years ago during an adventure and everyone has assumed the worst about her except for Totori, who goes looking for her.
- Action Mom
- Dead All Along: Finishing the game properly requires you to find her grave... however
A receptionist at the adventurers guild. She gives out quests to Totori when Totori is in Arland. Incredibly shy, she was forced to become a receptionist when her older sister Esty(from Atelier Rorona) suddenly quit.
The carriage driver in Alanya